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Colored Bands in CVD-Grown Diamond

Srushti Tanti and Raju Jain

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Figure 1. A growth remnant appeared as a color band (arrow) in a 3.14 ct CVD-grown diamond. Photomicrograph by Raju Jain; field of view ~11.75 mm.

Figure 2. A: Hazy parallel lines (indicated by arrows) resembling whitish internal graining. Photomicrograph by Raju Jain; field of view ~6.31 mm. DiamondView imaging of the pavilion facets showed blue growth layers in green fluorescence (B), as well as strong green phosphorescence (C). Images by Suraj Maurya.

The Surat laboratory recently examined a 3.14 ct F-color oval brilliant diamond grown by chemical vapor deposition (CVD). The diamond featured a single dark brown band measuring ~2.2 mm in length that resembled graining in natural diamond (figure 1). The band was visible under the microscope as well as with a 10× loupe. The clarity grade was VVS2 based on this colored band, which was visible through multiple bezels and affected the transparency at that location. Through the pavilion, parallel whitish bands were also observed (figure 2A).

Figure 3. False-color PL map of the SiV– defect at 736.6/736.9 nm using 633 nm laser excitation, normalized to the diamond Raman area on the pavilion. The dashed line indicates the approximate outline of the diamond.

The subtle banding seen in this diamond differed from a cloud of graphite inclusions at a growth interface previously reported in a CVD-grown diamond (Summer 2023 Lab Notes, pp. 213–214). The fluorescence image collected by the DiamondView revealed a layered growth structure that did not coincide with the color banding, indicating a start-stop cycling growth process typical of CVD synthesis (figure 2B). Deep UV fluorescence with green and blue coloration as well as strong green phosphorescence seen in the DiamondView image (figure 2C) indicated high-pressure, high-temperature treatment. The SiV– defect at 736.6 and 736.9 nm, a common feature of CVD laboratory-grown diamond and only rarely seen in natural diamond, was observed in photoluminescence (PL) spectra using 457, 514, and 633 nm laser excitation. PL mapping (figure 3) revealed that the concentration of SiV– was higher near the culet of the pavilion and dramatically lower near the table.

GIA has documented growth remnants in thousands of CVD-grown diamonds. But with a multitude of manufacturers, recipes, and treatments, a wide variety of clarity characteristics are encountered, including the unusual color band observed here.

Authors: Srushti Tanti is an analytics technician, and Raju Jain is a training specialist, at GIA in Surat, India.

This article was contributed by GIA® (Gemological Institute of America®)

GIA.edu | GIAindia.in

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Education

Material Science Is A Critical Component Of Jewellery Education

By Stephen Fernandes
– Design Tells A Piece What To Look Like. Material Science Determines Whether It Can Actually Exist and Endure.

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Jewellery education has long celebrated the visual: proportion, colour harmony, the poetry of form. But beneath every beautiful object lies a material reality that design alone cannot address. A ring may be conceived in sketches and rendered in digital light, yet it must ultimately exist as metal and stone in the physical world – subject to force, heat, chemical reaction, and time. It is material science, and specifically the disciplines of metallurgy and gemology, that equip students to navigate that reality with confidence and mastery.

This is not a peripheral concern. The structural decisions made at the bench – which alloy to choose, at what temperature to anneal, how to set a particular gemstone – are inseparable from the aesthetic ones. A jeweller who understands only visual composition is working half-blind.

Four Essential Pillars

Structural Integrity

Understanding ductility, hardness, and tensile strength is what separates a ring that endures from one that fails. The choice between 14k and 18k gold, for instance, is not merely economic – it is metallurgical. The higher copper content in 14k gold produces an alloy measurably harder and more resistant to the micro-deformations of daily wear, making it the practical choice for everyday pieces where an 18k ring might gradually lose its form.

Process Mastery

Annealing and work-hardening are not mere techniques – they are applied physics. Every time a jeweller draws wire through a draw plate, they are deliberately dislocating the metal’s crystalline structure to increase strength. Every time they introduce controlled heat, they are allowing those dislocations to resolve. Knowing exact alloy melting points, understanding eutectic behaviour in solder, and reading the colour of heated metal are skills that live entirely in the domain of materials science.

Gemstone Compatibility

A materials-informed approach transforms stone-setting from guesswork into precision. Sapphire, with a Mohs hardness of 9, demands a setting metal that will not score its girdle during bezel or prong work – typically platinum or a hardened gold alloy. Softer stones, conversely, may require specific burnishing tools and adjusted pressure. Without material knowledge, the setting process carries unnecessary risk to both the gem and mounting.

Sustainability & Innovation

The contemporary jeweller operates in an industry under increasing scrutiny. Modern education now encompasses recycled precious metals, ethically traceable stones, and experimental bio-based resins that challenge traditional making assumptions. Understanding the material properties of these alternatives – how recycled gold’s purity and grain structure may differ, how resins cure and age – is as technically demanding as working with conventional materials, and far more urgent.

The jeweller of the next decade will work across an increasingly complex material landscape, new alloys engineered for specific properties, lab-grown gems whose physical characteristics require fresh understanding, and sustainable alternatives that behave nothing like the conventional materials they replace. The studios and classrooms that treat material science as secondary – a footnote to design – are preparing students for a world that no longer exists.

Design is the language in which a jeweller speaks to the world. But material science is the grammar that makes the sentence hold together. Without it, the most beautiful concept remains just that – a concept, unable to survive contact with a hand, a prong, a hammer, or a decade of wear.

An education that integrates both is not splitting its attention between two disciplines. It is recognising that they were never truly separate to begin with.

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